钙同位素在古海洋研究中的应用及进展

陈西源; 周锡强; 孙剑; 高炳宇; 李润; 汤冬杰; 陈西源; 周锡强; 孙剑; 高炳宇; 李润; 汤冬杰

doi:10.14027/j.issn.1000-0550.2022.055

[1]

Gussone N,Schmitt A D,Heuser A,et al. Calcium stable isotope geochemistry[M]. Berlin： Springer,2016： 1-260.

[2]

DePaolo D J. Calcium isotopic variations produced by biological,kinetic,radiogenic and nucleosynthetic processes[J]. Reviews in Mineralogy and Geochemistry,2004,55（1）： 255-288.

[3]

Fantle M S,Tipper E T. Calcium isotopes in the global biogeochemical Ca cycle： Implications for development of a Ca isotope proxy[J]. Earth-Science Reviews,2014,129： 148-177.

[4]

Griffith E M,Fantle M S. Calcium isotopes[M]. Cambridge： Cambridge University Press,2021： 1-28.

[5]

Fantle M S. Evaluating the Ca isotope proxy[J]. American Journal of Science,2010,310（3）： 194-230.

[6]

Chakrabarti R,Mondal S,Jacobson A D,et al. Review of techniques,challenges,and new developments for calcium isotope ratio measurements[J]. Chemical Geology,2021,581： 120398.

[7]

Dai W,Moynier F,Paquet M,et al. Calcium isotope measurements using a collision cell （CC）-MC-ICP-MS[J]. Chemical Geology,2022,590： 120688.

[8]

Gussone N,Eisenhauer A,Heuser A,et al. Model for kinetic effects on calcium isotope fractionation （δ⁴⁴Ca） in inorganic aragonite and cultured planktonic foraminifera[J]. Geochimica et Cosmochimica Acta,2003,67（7）： 1375-1382.

[9]

Lemarchand D,Wasserburg G J,Papanastassiou D A. Rate-controlled calcium isotope fractionation in synthetic calcite[J]. Geochimica et Cosmochimica Acta,2004,68（22）： 4665-4678.

[10]

Marriott C S,Henderson G M,Belshaw N S,et al. Temperature dependence of δ ⁷Li,δ ⁴⁴Ca and Li/Ca during growth of calcium carbonate[J]. Earth and Planetary Science Letters,2004,222（2）： 615-624.

[11]

DePaolo D J. Surface kinetic model for isotopic and trace element fractionation during precipitation of calcite from aqueous solutions[J]. Geochimica et Cosmochimica Acta,2011,75（4）： 1039-1056.

[12]

Nielsen L C,DePaolo D J,De Yoreo J J. Self-consistent ion-by-ion growth model for kinetic isotopic fractionation during calcite precipitation[J]. Geochimica et Cosmochimica Acta,2012,86： 166-181.

[13]

Fantle M S,DePaolo D J. Ca isotopes in carbonate sediment and pore fluid from ODP Site 807A： The Ca²⁺（aq）-calcite equilibrium fractionation factor and calcite recrystallization rates in Pleistocene sediments[J]. Geochimica et Cosmochimica Acta,2007,71（10）： 2524-2546.

[14]

Blättler C L,Miller N R,Higgins J A. Mg and Ca isotope signatures of authigenic dolomite in siliceous deep-sea sediments[J]. Earth and Planetary Science Letters,2015,419： 32-42.

[15]

Blättler C L,Hong W L,Kirsimäe K,et al. Small calcium isotope fractionation at slow precipitation rates in methane seep authigenic carbonates[J]. Geochimica et Cosmochimica Acta,2021,298： 227-239.

[16]

Kang J T,Ionov D A,Liu F,et al. Calcium isotopic fractionation in mantle peridotites by melting and metasomatism and Ca isotope composition of the bulk silicate earth[J]. Earth and Planetary Science Letters,2017,474： 128-137.

[17]

Liu F,Li X,Wang G Q,et al. Marine carbonate component in the mantle beneath the southeastern Tibetan Plateau： Evidence from magnesium and calcium isotopes[J]. Journal of Geophysical Research： Solid Earth,2017,122（12）： 9729-9744.

[18]

Dai W,Wang Z C,Liu Y S,et al. Calcium isotope compositions of mantle pyroxenites[J]. Geochimica et Cosmochimica Acta,2020,270： 144-159.

[19]

Chen C F,Ciazela J,Li W,et al. Calcium isotopic compositions of oceanic crust at various spreading rates[J]. Geochimica et Cosmochimica Acta,2020,278： 272-288.

[20]

Sun J,Zhu X K,Belshaw N S,et al. Ca isotope systematics of carbonatites： Insights into carbonatite source and evolution[J]. Geochemical Perspectives Letters,2021,17： 11-15.

[21]

刘占民,刘丛强,韩贵琳,等. 钙同位素方法在环境地球化学研究中的应用与进展[J]. 地球与环境,2005,33（1）：71-78.

Liu Zhanmin,Liu Congqiang,Han Guilin,et al. Advances in applications of calcium isotopes in environmental geochemistry research[J]. Earth and Environment,2005,33（1）： 71-78.

[22]

李亮,蒋少涌. 钙同位素地球化学研究进展[J]. 中国地质,2008,35（6）：1088-1100.

Li Liang,Jiang Shaoyong. Advance in calcium isotope geochemistry[J]. Geology in China,2008,35（6）： 1088-1100.

[23]

吴能友,张必东,邬黛黛. 海洋钙同位素分馏机制及其古海洋学应用[J]. 地球科学进展,2015,30（4）：433-444.

Wu Neng- you,Zhang Bidong,Wu Daidai. Fractionation mechanism and paleoceanographic applications of calcium isotopes in marine settings[J]. Advances in Earth Science,2015,30（4）： 433-444.

[24]

祝红丽,张兆峰,刘峪菲,等. 钙同位素地球化学综述[J]. 地学前缘,2015,22（5）：44-53.

Zhu Hongli,Zhang Zhaofeng,Liu Yufei,et al. Calcium isotope geochemistry review[J]. Earth Science Frontiers,2015,22（5）： 44-53.

[25]

童铄云,冯兰平,刘金存,等. 钙同位素分析测试技术进展[J]. 矿物岩石地球化学通报,2016,35（3）：487-496.

Tong Shuoyun,Feng Lanping,Liu Jincun,et al. A review on the development of Ca isotope analytical techniques[J]. Bulletin of Mineralogy,Petrology and Geochemistry,2016,35（3）： 487-496.

[26]

Wang S H,Yan W,Magalhães H V,et al. Calcium isotope fractionation and its controlling factors over authigenic carbonates in the cold seeps of the northern South China Sea[J]. Chinese Science Bulletin,2012,57（11）： 1325-1332.

[27]

Wang S H,Yan W,Magalhães V H,et al. Factors influencing methane-derived authigenic carbonate formation at cold seep from southwestern Dongsha area in the northern South China Sea[J]. Environmental Earth Sciences,2014,71（5）： 2087-2094.

[28]

Chen X F,Deng W F,Zhu H L,et al. Assessment of coral δ^44/40Ca as a paleoclimate proxy in the Great Barrier Reef of Australia[J]. Chemical Geology,2016,435： 71-78.

[29]

Wei G Y,Hood A V S,Chen X,et al. Ca and Sr isotope constraints on the formation of the Marinoan cap dolostones[J]. Earth and Planetary Science Letters,2019,511： 202-212.

[30]

Zhao H,Dahl T W,Chen Z Q,et al. Anomalous marine calcium cycle linked to carbonate factory change after the Smithian Thermal Maximum （Early Triassic）[J]. Earth-Science Reviews,2020,211： 103418.

[31]

Cui Y,Zhang F F,Wang J Y,et al. Marine anoxia and ocean acidification during the end‐Permian extinction： An integrated view from δ²³⁸U and δ^44/40Ca proxies and earth system modeling[M]//Ernst R E,Dickson A J,Bekker A. Large igneous provinces： A driver of global environmental and biotic changes. Hoboken： Wiley,2021： 325-340.

[32]

Song H J,Song H Y,Tong J N,et al. Conodont calcium isotopic evidence for multiple shelf acidification events during the Early Triassic[J]. Chemical Geology,2021,562： 120038.

[33]

Fantle M S,Ridgwell A. Towards an understanding of the Ca isotopic signal related to ocean acidification and alkalinity overshoots in the rock record[J]. Chemical Geology,2020,547： 119672.

[34]

le Houedec S,McCulloch M,Trotter J,et al. Conodont apatite δ^88/86Sr and δ^44/40Ca compositions and implications for the evolution of Palaeozoic to Early Mesozoic seawater[J]. Chemical Geology,2017,453： 55-65.

[35]

Erhardt A M,Turchyn A V,Bradbury H J,et al. The calcium isotopic composition of carbonate hardground cements： A new record of changes in ocean chemistry?[J]. Chemical Geology,2020,540： 119490.

[36]

周锡强,陈代钊,刘牧,等. 中国沉积学发展战略：沉积地球化学研究现状与展望[J]. 沉积学报,2017,35（6）：1293-1316.

Zhou Xiqiang,Chen Daizhao,Liu Mu,et al. The future of sedimentology in China： A review and perspective of sedimentary geochemistry[J]. Acta Sedimentologica Sinica,2017,35（6）： 1293-1316.

[37]

Gussone N,Ahm A S C,Lau K V,et al. Calcium isotopes in deep time： Potential and limitations[J]. Chemical Geology,2020,544： 119601.

[38]

Farkaš J,Böhm F,Wallmann K,et al. Calcium isotope record of Phanerozoic oceans： Implications for chemical evolution of seawater and its causative mechanisms[J]. Geochimica et Cosmochimica Acta,2007,71（21）： 5117-5134.

[39]

Farkaš J,Buhl D,Blenkinsop J,et al. Evolution of the oceanic calcium cycle during the Late Mesozoic： Evidence from δ^44/40Ca of marine skeletal carbonates[J]. Earth and Planetary Science Letters,2007,253（1/2）： 96-111.

[40]

Blättler C L,Jenkyns H C,Reynard L M,et al. Significant increases in global weathering during Oceanic Anoxic Events 1a and 2 indicated by calcium isotopes[J]. Earth and Planetary Science Letters,2011,309（1/2）： 77-88.

[41]

Blättler C L,Henderson G M,Jenkyns H C. Explaining the Phanerozoic Ca isotope history of seawater[J]. Geology,2012,40（9）： 843-846.

[42]

Payne J L,Turchyn A V,Paytan A,et al. Calcium isotope constraints on the end-Permian mass extinction[J]. Proceedings of the National Academy of Sciences of the United States of America,2010,107（19）： 8543-8548.

[43]

Komar N,Zeebe R E. Oceanic calcium changes from enhanced weathering during the Paleocene-Eocene thermal maximum： No effect on calcium-based proxies[J]. Paleoceanography,2011,26（3）： PA3211.

[44]

Griffith E M,Fantle M S,Eisenhauer A,et al. Effects of ocean acidification on the marine calcium isotope record at the Paleocene-Eocene Thermal Maximum[J]. Earth and Planetary Science Letters,2015,419： 81-92.

[45]

Ahm A S C,Maloof A C,Macdonald F A,et al. An early diagenetic deglacial origin for basal Ediacaran "cap dolostones"[J]. Earth and Planetary Science Letters,2019,506： 292-307.

[46]

Ahm A S C,Bjerrum C J,Blättler C L,et al. Quantifying early marine diagenesis in shallow-water carbonate sediments[J]. Geochimica et Cosmochimica Acta,2018,236： 140-159.

[47]

Higgins J A,Blättler C L,Lundstrom E A,et al. Mineralogy,early marine diagenesis,and the chemistry of shallow-water carbonate sediments[J]. Geochimica et Cosmochimica Acta,2018,220： 512-534.

[48]

Busch J F,Hodgin E B,Ahm A S C,et al. Global and local drivers of the Ediacaran Shuram carbon isotope excursion[J]. Earth and Planetary Science Letters,2022,579： 117368.

[49]

Ahm A S C,Bjerrum C J,Hoffman P F,et al. The Ca and Mg isotope record of the Cryogenian Trezona carbon isotope excursion[J]. Earth and Planetary Science Letters,2021,568： 117002.

[50]

de Laeter J R,Bohlke J K,de Bièvre P J,et al. Atomic weights of the elements： Review 2000[J]. Pure and Applied Chemistry,2003,75（6）： 683-800.

[51]

Becker J S,Füllner K,Seeling U D,et al. Measuring magnesium,calcium and potassium isotope ratios using ICP-QMS with an octopole collision cell in tracer studies of nutrient uptake and translocation in plants[J]. Analytical and Bioanalytical Chemistry,2008,390（2）： 571-578.

[52]

Russell W A,Papanastassiou D A,Tombrello T A. Ca isotope fractionation on the Earth and other solar system materials[J]. Geochimica et Cosmochimica Acta,1978,42（8）： 1075-1090.

[53]

Halicz L,Galy A,Belshaw N S,et al. High-precision measurement of calcium isotopes in carbonates and related materials by multiple collector inductively coupled plasma mass spectrometry （MC-ICP-MS）[J]. Journal of Analytical Atomic Spectrometry,1999,14（12）： 1835-1838.

[54]

Tacail T,Télouk P,Balter V. Precise analysis of calcium stable isotope variations in biological apatites using laser ablation MC-ICPMS[J]. Journal of Analytical Atomic Spectrometry,2016,31（1）： 152-162.

[55]

Zhang W,Hu Z C,Liu Y S,et al. In situ calcium isotopic ratio determination in calcium carbonate materials and calcium phosphate materials using laser ablation-multiple collector-inductively coupled plasma mass spectrometry[J]. Chemical Geology,2019,522： 16-25.

[56]

Hippler D,Schmitt A D,Gussone N,et al. Calcium isotopic composition of various reference materials and seawater[J]. Geostandards Newsletter,2003,27（1）： 13-19.

[57]

Amini M,Eisenhauer A,Böhm F,et al. Calcium isotope （δ^44/40Ca） fractionation along hydrothermal pathways,Logatchev field （Mid-Atlantic Ridge,14°45'N）[J]. Geochimica et Cosmochimica Acta,2008,72（16）： 4107-4122.

[58]

Heuser A,Eisenhauer A. The calcium isotope composition （δ^44/40Ca） of NIST SRM 915b and NIST SRM 1486[J]. Geostandards and Geoanalytical Research,2008,32（3）： 311-315.

[59]

Reynard L M,Henderson G M,Hedges R E M. Calcium isotopes in archaeological bones and their relationship to dairy consumption[J]. Journal of Archaeological Science,2011,38（3）： 657-664.

[60]

Holmden C,Papanastassiou D A,Blanchon P,et al. δ^44/40Ca variability in shallow water carbonates and the impact of submarine groundwater discharge on Ca-cycling in marine environments[J]. Geochimica et Cosmochimica Acta,2012,83： 179-194.

[61]

Morgan J L L,Skulan J L,Gordon G W,et al. Rapidly assessing changes in bone mineral balance using natural stable calcium isotopes[J]. Proceedings of the National Academy of Sciences of the United States of America,2012,109（25）： 9989-9994.

[62]

刘芳. 钙同位素分析方法及其地质应用：以腾冲火山岩和粤北碳酸盐风化壳为例[D]. 广州：中国科学院广州地球化学研究所,2018：1-153.

[63]

Griffith E M,Paytan A,Caldeira K,et al. A dynamic marine calcium cycle during the past 28 million years[J]. Science,2008,322（5908）： 1671-1674.

[64]

Blättler C L,Higgins J A. Calcium isotopes in evaporites record variations in Phanerozoic seawater SO₄ and Ca[J]. Geology,2014,42（8）： 711-714.

[65]

Gussone N,Böhm F,Eisenhauer A,et al. Calcium isotope fractionation in calcite and aragonite[J]. Geochimica et Cosmochimica Acta,2005,69（18）： 4485-4494.

[66]

Crockford P W,Kunzmann M,Blättler C L,et al. Reconstructing Neoproterozoic seawater chemistry from early diagenetic dolomite[J]. Geology,2021,49（4）： 442-446.

[67]

Tang J W,Dietzel M,Böhm F,et al. Sr²⁺/Ca²⁺ and ⁴⁴Ca/⁴⁰Ca fractionation during inorganic calcite formation： II. Ca isotopes[J]. Geochimica et Cosmochimica Acta,2008,72（15）： 3733-3745.

[68]

Tang J W,Niedermayr A,Köhler S J,et al. Sr²⁺/Ca²⁺ and ⁴⁴Ca/⁴⁰Ca fractionation during inorganic calcite formation： III. Impact of salinity/ionic strength[J]. Geochimica et Cosmochimica Acta,2012,77： 432-443.

[69]

Alkhatib M,Eisenhauer A. Calcium and strontium isotope fractionation during precipitation from aqueous solutions as a function of temperature and reaction rate； II. Aragonite[J]. Geochimica et Cosmochimica Acta,2017,209： 320-342.

[70]

Alkhatib M,Eisenhauer A. Calcium and strontium isotope fractionation in aqueous solutions as a function of temperature and reaction rate； I. Calcite[J]. Geochimica et Cosmochimica Acta,2017,209： 296-319.

[71]

Gussone N,Langer G,Geisen M,et al. Calcium isotope fractionation in coccoliths of cultured Calcidiscus leptoporus,Helicosphaera carteri,Syracosphaera pulchra and Umbilicosphaera foliosa [J]. Earth and Planetary Science Letters,2007,260（3/4）： 505-515.

[72]

Inoue M,Gussone N,Koga Y,et al. Controlling factors of Ca isotope fractionation in scleractinian corals evaluated by temperature,pH and light controlled culture experiments[J]. Geochimica et Cosmochimica Acta,2015,167： 80-92.

[73]

Zhu P,Macdougall J D. Calcium isotopes in the marine environment and the oceanic calcium cycle[J]. Geochimica et Cosmochimica Acta,1998,62（10）： 1691-1698.

[74]

Nägler T F,Eisenhauer A,Müller A,et al. The δ⁴⁴Ca-temperature calibration on fossil and cultured Globigerinoides sacculifer： New tool for reconstruction of past sea surface temperatures[J]. Geochemistry Geophysics Geosystems,2000,1（9）： 2000GC000091.

[75]

Gussone N,Hönisch B,Heuser A,et al. A critical evaluation of calcium isotope ratios in tests of planktonic foraminifers[J]. Geochimica et Cosmochimica Acta,2009,73（24）： 7241-7255.

[76]

Hippler D,Kozdon R,Darling K F,et al. Calcium isotopic composition of high-latitude proxy carrier Neogloboquadrina pachyderma （sin.）[J]. Biogeosciences,2009,6（1）： 1-14.

[77]

Kısakürek B,Eisenhauer A,Böhm F,et al. Controls on calcium isotope fractionation in cultured planktic foraminifera,Globigerinoides ruber and Globigerinella siphonifera [J]. Geochimica et Cosmochimica Acta,2011,75（2）： 427-443.

[78]

Sime N G,de la Rocha C L,Galy A. Negligible temperature dependence of calcium isotope fractionation in 12 species of planktonic foraminifera[J]. Earth and Planetary Science Letters,2005,232（1/2）： 51-66.

[79]

Böhm F,Gussone N,Eisenhauer A,et al. Calcium isotope fractionation in modern scleractinian corals[J]. Geochimica et Cosmochimica Acta,2006,70（17）： 4452-4462.

[80]

Gussone N,Langer G,Thoms S,et al. Cellular calcium pathways and isotope fractionation in Emiliania huxleyi [J]. Geology,2006,34（8）： 625-628.

[81]

Langer G,Gussone N,Nehrke G,et al. Calcium isotope fractionation during coccolith formation in Emiliania huxleyi： Independence of growth and calcification rate[J]. Geochemistry Geophysics Geosystems,2007,8（5）： Q05007.

[82]

Hippler D,Witbaard R,van Aken H M,et al. Exploring the calcium isotope signature of Arctica islandica as an environmental proxy using laboratory- and field-cultured specimens[J]. Palaeogeography,Palaeoclimatology,Palaeoecology,2013,373： 75-87.

[83]

Hoffmann R,Riechelmann S,Liebetrau V,et al. Calcium isotope values of modern and fossil cephalopod shells：Trophic level or proxy for seawater geochemistry?[J]. Chemical Geology,2021,583： 120466.

[84]

von Allmen K,Nägler T F,Pettke T,et al. Stable isotope profiles （Ca,O,C） through modern brachiopod shells of T. septentrionalis and G. vitreus： Implications for calcium isotope paleo-ocean chemistry[J]. Chemical Geology,2010,269（3/4）： 210-219.

[85]

Bradbury H J,Halloran K H,Lin C Y,et al. Calcium isotope fractionation during microbially induced carbonate mineral precipitation[J]. Geochimica et Cosmochimica Acta,2020,277： 37-51.

[86]

Hensley T M. Calcium isotopic variation in marine evaporites and carbonates： Applications to Late Miocene Mediterranean brine chemistry and Late Cenozoic calcium cycling in the oceans[D]. La Jolla： Scripps Institution of Oceanography,University of California,2006： 1-124.

[87]

Harouaka K,Eisenhauer A,Fantle M S. Experimental investigation of Ca isotopic fractionation during abiotic gypsum precipitation[J]. Geochimica et Cosmochimica Acta,2014,129： 157-176.

[88]

Griffith E M,Paytan A,Eisenhauer A,et al. Seawater calcium isotope ratios across the Eocene-Oligocene transition[J]. Geology,2011,39（7）： 683-686.

[89]

Griffith E M,Schauble E A,Bullen T D,et al. Characterization of calcium isotopes in natural and synthetic barite[J]. Geochimica et Cosmochimica Acta,2008,72（23）： 5641-5658.

[90]

Soudry D,Glenn C R,Nathan Y,et al. Evolution of Tethyan phosphogenesis along the northern edges of the Arabian-African shield during the Cretaceous-Eocene as deduced from temporal variations of Ca and Nd isotopes and rates of P accumulation[J]. Earth-Science Reviews,2006,78（1/2）： 27-57.

[91]

Schmitt A D,Stille P,Vennemann T. Variations of the ⁴⁴Ca/⁴⁰Ca ratio in seawater during the past 24 million years： Evidence from δ⁴⁴Ca and δ¹⁸O values of Miocene phosphates[J]. Geochimica et Cosmochimica Acta,2003,67（14）： 2607-2614.

[92]

Arning E T,Lückge A,Breuer C,et al. Genesis of phosphorite crusts off Peru[J]. Marine Geology,2009,262（1/2/3/4）： 68-81.

[93]

Skulan J,DePaolo D J,Owens T L. Biological control of calcium isotopic abundances in the global calcium cycle[J]. Geochimica et Cosmochimica Acta,1997,61（12）： 2505-2510.

[94]

刘康,周锡强,江茂生. 牙形刺氧同位素古温度计：研究进展与展望[J]. 沉积学报,2022,40（2）：396-409.

Liu Kang,Zhou Xiqiang,Jiang Maosheng. Oxygen isotope palaeothermometry of conodont apatite： A review[J]. Acta Sedimentologica Sinica,2022,40（2）： 396-409.

[95]

Sarmiento J L,Gruber N. Ocean biogeochemical dynamics[M]. Princeton： Princeton University Press,2006： 1-503.

[96]

Jacobson A D,Holmden C. δ⁴⁴Ca evolution in a carbonate aquifer and its bearing on the equilibrium isotope fractionation factor for calcite[J]. Earth and Planetary Science Letters,2008,270（3/4）： 349-353.

[97]

Berner E K,Berner R A. Global environment： Water,air,and geochemical cycles[M]. Upper Saddle River： Prentice Hall,1996： 1-376.

[98]

Adloff M,Ridgwell A,Monteiro F M,et al. Inclusion of a suite of weathering tracers in the cGENIE Earth system model- muffin release v.0.9.23[J]. Geoscientific Model Development,2021,14（7）： 4187-4223.

[99]

Wang J Y,Jacobson A D,Zhang H,et al. Coupled δ^44/40Ca,δ^88/86Sr,and ⁸⁷Sr/⁸⁶Sr geochemistry across the end-Permian mass extinction event[J]. Geochimica et Cosmochimica Acta,2019,262： 143-165.

[100]

Pruss S B,Blättler C L,Macdonald F A,et al. Calcium isotope evidence that the earliest metazoan biomineralizers formed aragonite shells[J]. Geology,2018,46（9）： 763-766.

[101]

Fantle M S. Calcium isotopic evidence for rapid recrystallization of bulk marine carbonates and implications for geochemical proxies[J]. Geochimica et Cosmochimica Acta,2015,148： 378-401.

[102]

Gothmann A M,Bender M L,Blättler C L,et al. Calcium isotopes in scleractinian fossil corals since the Mesozoic： Implications for vital effects and biomineralization through time[J]. Earth and Planetary Science Letters,2016,444： 205-214.

[103]

Lau K V,Maher K,Brown S T,et al. The influence of seawater carbonate chemistry,mineralogy,and diagenesis on calcium isotope variations in Lower-Middle Triassic carbonate rocks[J]. Chemical Geology,2017,471： 13-37.

[104]

Silva-Tamayo J C,Lau K V,Jost A B,et al. Global perturbation of the marine calcium cycle during the Permian-Triassic transition[J]. GSA Bulletin,2018,130（7/8）： 1323-1338.

[105]

Immenhauser A,Nägler T F,Steuber T,et al. A critical assessment of mollusk ¹⁸O/¹⁶O,Mg/Ca,and ⁴⁴Ca/⁴⁰Ca ratios as proxies for Cretaceous seawater temperature seasonality[J]. Palaeogeography,Palaeoclimatology,Palaeoecology,2005,215（3/4）： 221-237.

[106]

Steuber T,Buhl D. Calcium-isotope fractionation in selected modern and ancient marine carbonates[J]. Geochimica et Cosmochimica Acta,2006,70（22）： 5507-5521.

[107]

Hippler D,Eisenhauer A,Nägler T F. Tropical Atlantic SST history inferred from Ca isotope thermometry over the last 140ka[J]. Geochimica et Cosmochimica Acta,2006,70（1）： 90-100.

[108]

Sime N G,De La Rocha C L,Tipper E T,et al. Interpreting the Ca isotope record of marine biogenic carbonates[J]. Geochimica et Cosmochimica Acta,2007,71（16）： 3979-3989.

[109]

Hinojosa J L,Brown S T,Chen J,et al. Evidence for end-Permian ocean acidification from calcium isotopes in biogenic apatite[J]. Geology,2012,40（8）： 743-746.

[110]

Sulpis O,Jeansson E,Dinauer A,et al. Calcium carbonate dissolution patterns in the ocean[J]. Nature Geoscience,2021,14（6）： 423-428.

[111]

Shields G A,Mills B J W,Zhu M Y,et al. Unique Neoproterozoic carbon isotope excursions sustained by coupled evaporite dissolution and pyrite burial[J]. Nature Geoscience,2019,12（10）： 823-827.

[112]

de la Rocha C L,DePaolo D J. Isotopic evidence for variations in the marine calcium cycle over the Cenozoic[J]. Science,2000,289（5482）： 1176-1178.

[113]

Tipper E T,Gaillardet J,Galy A,et al. Calcium isotope ratios in the world's largest rivers： A constraint on the maximum imbalance of oceanic calcium fluxes[J]. Global Biogeochemical Cycles,2010,24（3）： GB3019.

[114]

Griffith E M,Schmitt A D,Andrews M G,et al. Elucidating modern geochemical cycles at local,regional,and global scales using calcium isotopes[J]. Chemical Geology,2020,534： 119445.

[115]

Cenki-Tok B,Chabaux F,Lemarchand D,et al. The impact of water-rock interaction and vegetation on calcium isotope fractionation in soil- and stream waters of a small,forested catchment （the Strengbach case）[J]. Geochimica et Cosmochimica Acta,2009,73（8）： 2215-2228.

[116]

Milliman J D. Production and accumulation of calcium carbonate in the ocean： Budget of a nonsteady state[J]. Global Biogeochemical Cycles,1993,7（4）： 927-957.

[117]

Schmitt A D,Chabaux F,Stille P. The calcium riverine and hydrothermal isotopic fluxes and the oceanic calcium mass balance[J]. Earth and Planetary Science Letters,2003,213（3/4）： 503-518.

[118]

Fantle M S,Barnes B D,Lau K V. The role of diagenesis in shaping the geochemistry of the marine carbonate record[J]. Annual Review of Earth and Planetary Sciences,2020,48（1）： 549-583.

[119]

Bradbury H J,Turchyn A V. Calcium isotope fractionation in sedimentary pore fluids from ODP Leg 175： Resolving carbonate recrystallization[J]. Geochimica et Cosmochimica Acta,2018,236： 121-139.

[120]

James D H,Bradbury H J,Antler G,et al. Assessing sedimentary boundary layer calcium carbonate precipitation and dissolution using the calcium isotopic composition of pore fluids[J]. Frontiers in Earth Science,2021,9： 601194.

[121]

Fantle M S,Higgins J. The effects of diagenesis and dolomitization on Ca and Mg isotopes in marine platform carbonates： Implications for the geochemical cycles of Ca and Mg[J]. Geochimica et Cosmochimica Acta,2014,142： 458-481.

[122]

Ahm A S,Husson J. Local and global controls on carbon isotope chemostratigraphy[M]. Cambridge： Cambridge University Press,2022： 1-28.

[123]

Fantle M S,DePaolo D J. Variations in the marine Ca cycle over the past 20 million years[J]. Earth and Planetary Science Letters,2005,237（1/2）： 102-117.

[124]

Heuser A,Eisenhauer A,Böhm F,et al. Calcium isotope （δ^44/40Ca） variations of Neogene planktonic foraminifera[J]. Paleoceanography,2005,20（2）： PA2013.

[125]

Zhou X Q,Chen D Z,Dong S F,et al. Diagenetic barite deposits in the Yurtus Formation in Tarim Basin,NW China： Implications for barium and sulfur cycling in the earliest Cambrian[J]. Precambrian Research,2015,263： 79-87.

[126]

周锡强,遇昊,黄泰誉,等. 重晶石沉积类型及成因评述：兼论扬子地区下寒武统重晶石的富集机制[J]. 沉积学报,2016,34（6）：1044-1056.

Zhou Xiqiang,Yu Hao,Huang Taiyu,et al. Genetic classification of sedimentary barites and discussion on the origin of the Lower Cambrian barite-rich deposits in the Yangtze Block,South China[J]. Acta Sedimentologica Sinica,2016,34（6）： 1044-1056.

[127]

Stanley S M,Hardie L A. Secular oscillations in the carbonate mineralogy of reef-building and sediment-producing organisms driven by tectonically forced shifts in seawater chemistry[J]. Palaeogeography,Palaeoclimatology,Palaeoecology,1998,144（1/2）： 3-19.

[128]

Farkaš J,Frýda J,Holmden C. Calcium isotope constraints on the marine carbon cycle and CaCO₃ deposition during the Late Silurian （Ludfordian） positive δ ¹³C excursion[J]. Earth and Planetary Science Letters,2016,451： 31-40.

[129]

Kasemann S A,von Strandmann P A E P,Prave A R,et al. Continental weathering following a Cryogenian glaciation： Evidence from calcium and magnesium isotopes[J]. Earth and Planetary Science Letters,2014,396： 66-77.

[130]

Hoffman P F,Abbot D S,Ashkenazy Y,et al. Snowball Earth climate dynamics and Cryogenian geology-geobiology[J]. Science Advances,2017,3（11）： e1600983.

[131]

Sawaki Y,Tahata M,Ohno T,et al. The anomalous Ca cycle in the Ediacaran ocean： Evidence from Ca isotopes preserved in carbonates in the Three Gorges area,South China[J]. Gondwana Research,2014,25（3）： 1070-1089.

[132]

Kasemann S A,Hawkesworth C J,Prave A R,et al. Boron and calcium isotope composition in Neoproterozoic carbonate rocks from Namibia： Evidence for extreme environmental change[J]. Earth and Planetary Science Letters,2005,231（1/2）： 73-86.

[133]

Silva-Tamayo J C,Nägler T F,Sial A N,et al. Global perturbation of the marine Ca isotopic composition in the aftermath of the Marinoan global glaciation[J]. Precambrian Research,2010,182（4）： 373-381.

[134]

Zachos J C,Dickens G R,Zeebe R E. An Early Cenozoic perspective on greenhouse warming and carbon-cycle dynamics[J]. Nature,2008,451（7176）： 279-283.

[135]

Chen Z L,Wang X,Hu J F,et al. Structure of the carbon isotope excursion in a high-resolution lacustrine Paleocene-Eocene thermal maximum record from central China[J]. Earth and Planetary Science Letters,2014,408： 331-340.