沾化凹陷生油岩的裂解色谱、裂解色谱&mdash;质谱分析及地球化学意义

史继扬; R.P.菲耳普

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沾化凹陷生油岩的裂解色谱、裂解色谱—质谱分析及地球化学意义

史继扬, R.P.菲耳普

文章导航 > 沉积学报 > 1985 > 3(3): 65-73

史继扬, R.P.菲耳普. 沾化凹陷生油岩的裂解色谱、裂解色谱—质谱分析及地球化学意义[J]. 沉积学报, 1985, 3(3): 65-73.

引用本文:

史继扬, R.P.菲耳普. 沾化凹陷生油岩的裂解色谱、裂解色谱—质谱分析及地球化学意义[J]. 沉积学报, 1985, 3(3): 65-73.

Shi Jiyang, R.P.Philp. PY-GC, PY-GC-MS ANALYSES OF SOURCE ROCKS FROM ZHANHUA DEPRESSION AND THEIR GEOCHEMICAL SIGNIFICANCE[J]. Acta Sedimentologica Sinica, 1985, 3(3): 65-73.

Citation:

Shi Jiyang, R.P.Philp. PY-GC, PY-GC-MS ANALYSES OF SOURCE ROCKS FROM ZHANHUA DEPRESSION AND THEIR GEOCHEMICAL SIGNIFICANCE[J]. Acta Sedimentologica Sinica, 1985, 3(3): 65-73.

史继扬, R.P.菲耳普. 沾化凹陷生油岩的裂解色谱、裂解色谱—质谱分析及地球化学意义[J]. 沉积学报, 1985, 3(3): 65-73.

引用本文:

史继扬, R.P.菲耳普. 沾化凹陷生油岩的裂解色谱、裂解色谱—质谱分析及地球化学意义[J]. 沉积学报, 1985, 3(3): 65-73.

Shi Jiyang, R.P.Philp. PY-GC, PY-GC-MS ANALYSES OF SOURCE ROCKS FROM ZHANHUA DEPRESSION AND THEIR GEOCHEMICAL SIGNIFICANCE[J]. Acta Sedimentologica Sinica, 1985, 3(3): 65-73.

Citation:

Shi Jiyang, R.P.Philp. PY-GC, PY-GC-MS ANALYSES OF SOURCE ROCKS FROM ZHANHUA DEPRESSION AND THEIR GEOCHEMICAL SIGNIFICANCE[J]. Acta Sedimentologica Sinica, 1985, 3(3): 65-73.

沾化凹陷生油岩的裂解色谱、裂解色谱—质谱分析及地球化学意义

史继扬¹,
R.P.菲耳普²

1.
中国科学院地球化学所;
2.
澳大利亚联邦科学工业研究组织化石燃料部

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PY-GC, PY-GC-MS ANALYSES OF SOURCE ROCKS FROM ZHANHUA DEPRESSION AND THEIR GEOCHEMICAL SIGNIFICANCE

Shi Jiyang¹,
R.P.Philp²

1.
Institute of Geochemistry, Academia Sinica;
2.
CSIRO Division of Fossil Fuets, Australia

摘要

摘要: 有机地球化学研究中,目前大量的报导是对地质样品中可溶有机质的组成、结构的研究。可溶有机质中正烷烃偶奇优势,甾、萜分布等,已广泛用于油、气勘探,评价生油岩有机质母质来源、成熟度和对比油源。但可溶有机质碳含量占生油岩中有机碳不到百分之五,生油岩中大部分有机质是以干酪根形式存在,油、气的成因与干酪根密切相关。近年来,裂解色谱、裂解色谱-质谱已用于研究干酪根中结合烃类的组成、结构,并用于指示沉积岩中有机质的成熟度、母质输入等^[1、2、2],我国近年来也开始研究干酪根的裂解色谱¹⁾，本文则报导利用裂解色谱、裂解色谱一质谱研究一个已知地球化学剖面沉积有机质成熟度和沉积环境的尝试，探索建立评价生油岩成熟度的快速、有效的有机地球化学方法。

Abstract: The source rocks from the first,third and fourth sections of Shahejie formation of Zhanhua depression have been analyzed by PY-GC and PY-GC-MS in this study and a detective method of multiple ions is employed to determine the triterpanes and triterpenes in the source rocks. The pyro-chromatograms of the source rocks of Zhanhua depression show that the distribution of n-alkane/n-alkene doublets is broad and that the first section and third section of the Shahejie formation have a n-alkane/n-alkene doublet distribution with odd over even preference and higher Pr/Ph ratio. On the contrary,the pyro-chromatogram of the forth section has n-alkane/n-alkene doublet distribution with an even over odd prefeence and lower Pr/Ph ratio. Thus, the fourth section of Shahejie formation is suggested as a saline lake sedimentation with reducing environment and that these indexes, such as n-alkane/n-alkene doublets distribution and Pr/Ph ratio, etc., can be used as the criteria of a sedimentary envirnment. The PY-GC, PY-GC-MS chromatograms of the source rocks of Zhanhua depression show that the insoluble organic matters, such as prist-l-ene/n-C17, C30 Ho-pane, 17β(H(21α(H)/17α(H)21β(H), C₂₇Hopane 17β(H)/17a(H) C₂₇Hopene/C₂₇ 17α(H)Hopane, etc. decrease with increasing maturity of the samples, and that C₃₁ Hopane, 17α(H)21β(H)22S/17α(H)21β(H) 22(R+S)% increase with increasing maturity of the samples/ As a result, they demonstrate that these parameters can be employed to measure the maturity of organic matters in sediment. However, the result of the present study has shown that PY-GC and PY-GC-MS are useful means to evaluate the deposition environment of source rocks and its maturity.

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参考文献(1)

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(1)史继扬等，1982，胜利油田原油和生油岩中的生物标志化合物及其应用，地球化学1期4 -200

(2)S.R .Larter, et.al.，1979,0 ccurrence and Significance of Prist-1-ene in K erogen Pyrolysates, N ature, 279, 405-408.

(3)A .L.Chaffee, et al.，1983,Pyrolysis-Gas Chromatography of Australian Coals.I, Victorian Brown Coal Lithotypes, Fuel, 62, 311-316.

(4)S. R. Larter, et al.，1978, Pyrolysis-GC-MS of Kerogen, J. Chromatog.，167,421-431.

(5)D. Van De Meet, et al.，1980, Pyrolysis-High Resolution Gas Chromatography and Pyrolysis Gas Chromatography-Mass Spectrometry of Kerogen and Kerogen Precursors, Geochim Cosmochim Acta 44, 999-1013.

(6)E.J .Gallegos, 1975,PGC-MS Analysis of Kerogen in Green River Shale, Anal.Chem 47, 1524.

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沾化凹陷生油岩的裂解色谱、裂解色谱—质谱分析及地球化学意义

史继扬¹,
R.P.菲耳普²

1. 中国科学院地球化学所;

2. 澳大利亚联邦科学工业研究组织化石燃料部

收稿日期: 1984-09-26
刊出日期: 1985-09-10

摘要: 有机地球化学研究中,目前大量的报导是对地质样品中可溶有机质的组成、结构的研究。可溶有机质中正烷烃偶奇优势,甾、萜分布等,已广泛用于油、气勘探,评价生油岩有机质母质来源、成熟度和对比油源。但可溶有机质碳含量占生油岩中有机碳不到百分之五,生油岩中大部分有机质是以干酪根形式存在,油、气的成因与干酪根密切相关。近年来,裂解色谱、裂解色谱-质谱已用于研究干酪根中结合烃类的组成、结构,并用于指示沉积岩中有机质的成熟度、母质输入等^[1、2、2],我国近年来也开始研究干酪根的裂解色谱¹⁾，本文则报导利用裂解色谱、裂解色谱一质谱研究一个已知地球化学剖面沉积有机质成熟度和沉积环境的尝试，探索建立评价生油岩成熟度的快速、有效的有机地球化学方法。

English Abstract

PY-GC, PY-GC-MS ANALYSES OF SOURCE ROCKS FROM ZHANHUA DEPRESSION AND THEIR GEOCHEMICAL SIGNIFICANCE

Shi Jiyang¹,
R.P.Philp²

1. Institute of Geochemistry, Academia Sinica;

2. CSIRO Division of Fossil Fuets, Australia

Received Date: 1984-09-26
Publish Date: 1985-09-10

Abstract: The source rocks from the first,third and fourth sections of Shahejie formation of Zhanhua depression have been analyzed by PY-GC and PY-GC-MS in this study and a detective method of multiple ions is employed to determine the triterpanes and triterpenes in the source rocks. The pyro-chromatograms of the source rocks of Zhanhua depression show that the distribution of n-alkane/n-alkene doublets is broad and that the first section and third section of the Shahejie formation have a n-alkane/n-alkene doublet distribution with odd over even preference and higher Pr/Ph ratio. On the contrary,the pyro-chromatogram of the forth section has n-alkane/n-alkene doublet distribution with an even over odd prefeence and lower Pr/Ph ratio. Thus, the fourth section of Shahejie formation is suggested as a saline lake sedimentation with reducing environment and that these indexes, such as n-alkane/n-alkene doublets distribution and Pr/Ph ratio, etc., can be used as the criteria of a sedimentary envirnment. The PY-GC, PY-GC-MS chromatograms of the source rocks of Zhanhua depression show that the insoluble organic matters, such as prist-l-ene/n-C17, C30 Ho-pane, 17β(H(21α(H)/17α(H)21β(H), C₂₇Hopane 17β(H)/17a(H) C₂₇Hopene/C₂₇ 17α(H)Hopane, etc. decrease with increasing maturity of the samples, and that C₃₁ Hopane, 17α(H)21β(H)22S/17α(H)21β(H) 22(R+S)% increase with increasing maturity of the samples/ As a result, they demonstrate that these parameters can be employed to measure the maturity of organic matters in sediment. However, the result of the present study has shown that PY-GC and PY-GC-MS are useful means to evaluate the deposition environment of source rocks and its maturity.

史继扬, R.P.菲耳普. 沾化凹陷生油岩的裂解色谱、裂解色谱—质谱分析及地球化学意义[J]. 沉积学报, 1985, 3(3): 65-73.

引用本文:

史继扬, R.P.菲耳普. 沾化凹陷生油岩的裂解色谱、裂解色谱—质谱分析及地球化学意义[J]. 沉积学报, 1985, 3(3): 65-73.

Shi Jiyang, R.P.Philp. PY-GC, PY-GC-MS ANALYSES OF SOURCE ROCKS FROM ZHANHUA DEPRESSION AND THEIR GEOCHEMICAL SIGNIFICANCE[J]. Acta Sedimentologica Sinica, 1985, 3(3): 65-73.

Citation:

Shi Jiyang, R.P.Philp. PY-GC, PY-GC-MS ANALYSES OF SOURCE ROCKS FROM ZHANHUA DEPRESSION AND THEIR GEOCHEMICAL SIGNIFICANCE[J]. Acta Sedimentologica Sinica, 1985, 3(3): 65-73.

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沾化凹陷生油岩的裂解色谱、裂解色谱—质谱分析及地球化学意义

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PY-GC, PY-GC-MS ANALYSES OF SOURCE ROCKS FROM ZHANHUA DEPRESSION AND THEIR GEOCHEMICAL SIGNIFICANCE

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沾化凹陷生油岩的裂解色谱、裂解色谱—质谱分析及地球化学意义

1. 中国科学院地球化学所;

2. 澳大利亚联邦科学工业研究组织化石燃料部

English Abstract

PY-GC, PY-GC-MS ANALYSES OF SOURCE ROCKS FROM ZHANHUA DEPRESSION AND THEIR GEOCHEMICAL SIGNIFICANCE

1. Institute of Geochemistry, Academia Sinica;

2. CSIRO Division of Fossil Fuets, Australia

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沾化凹陷生油岩的裂解色谱、裂解色谱—质谱分析及地球化学意义

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PY-GC, PY-GC-MS ANALYSES OF SOURCE ROCKS FROM ZHANHUA DEPRESSION AND THEIR GEOCHEMICAL SIGNIFICANCE

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出版历程

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沾化凹陷生油岩的裂解色谱、裂解色谱—质谱分析及地球化学意义

1. 中国科学院地球化学所; 2. 澳大利亚联邦科学工业研究组织化石燃料部

English Abstract

PY-GC, PY-GC-MS ANALYSES OF SOURCE ROCKS FROM ZHANHUA DEPRESSION AND THEIR GEOCHEMICAL SIGNIFICANCE

1. Institute of Geochemistry, Academia Sinica; 2. CSIRO Division of Fossil Fuets, Australia

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1. 中国科学院地球化学所;

2. 澳大利亚联邦科学工业研究组织化石燃料部

1. Institute of Geochemistry, Academia Sinica;

2. CSIRO Division of Fossil Fuets, Australia