Applied Models of Rare Gas Geochemistry in the Research of Natural Gases
-
摘要: 在对天然气稀有气体地球化学特征进行系统研究的基础上，建立了有关氦、氩同位素组成的横“人”字型的成因模式并提出两种成因类型：Ａ、壳－幔复合型；Ｂ、壳源型。同时，还论述了稀有气体的年代积累效应与气源对比，进行了大、中型气区天然气地球化学综合研究。Abstract: A large number of valuable analytic data of the chemical compositions and isotopes of natural gases have been obtained from 532 natural gas samples of 19 oil - gas - bearing basins in China. On the basis of the comprehensive research of the characteristics of natural gases it has been considered that the space distribution of the content and isotopic composition of rare gases in natural gases were controlled by tectonic settings. According to the 3He/ 4He values the distribution of the He isotopes in the oil - bearing basins can be divided into four areas: (1) eastern active area, where the natural gases of the basins near the Tancheng - Lujiang Fault have an average 3He/ 4He value of 10 -6, suggesting the addition of the mantle - derived volatile components, and the natural gases of the basins far from the Tancheng - Lujiang Fault have a mean 3He/ 4He value of 10 -7; (2) middle stable area, where the natural gases of the basins have an average 3He/ 4He value of 4× 10 -8, minimum of 5 × 10 -9, which means that He was monoradioactive; (3) northwest substable area,where the natural gases of the basins have a range of 3He/4He values from 10 -8 to 10 -7; and (4) southwest area of Hainal Island, along both sides of Honghe River Fault, where the natural gases of the basins have a range of 3He/ 4He ratio from 10 -8 to 10 -7 and averages 10 -7, indicating that He was crust - derived. A reverse Y- shaped origin model of rare gases has been proposed and two-origin types have been provided:(a) Crust - and mantte - derived type, distributed in the eastern active area, where the 40Ar/ 36Ar and 3He/ 4He values of rare gases increase with the addition of mantle - derived gases and (b) crust - derived type, distributed in the stable and substable area of Centrol and West China, cbaractermng that the 40Ar/ 36Ar values of rare gases increase but the 3He/4He values decrease with geological ages. Meanwhile, the time - accumulating - effect of Ar and He isotopes in natural gases is also researched. The formula which can be used to calculate the ages of crust -derived gas source rocks using He and Ar isotopic methods is suggested.The formula can be applied to tracing and comparating gas source rocks, which is of practical signficance for gas exploration. In addition, the rare gas geochemistry, hydrocarbon gas geochemistry, and the related geological backgrounds of the central north gas area of Erdos Basin, the Chuandong gas area of Sichuan Basin,the Ya 13 -1 gas fields and the Dengfang- Ledong gas zone have comprehensively been researched and some new views on the three large - or middle - sized gas areas have been suggested.
-
[1] 1.徐水昌、沈平、肉明信等,1994，中国含油气盆地天然气中氮同位素分布，科学通报，39(16):1505-1508。
2.Kaneoka, I. and Takaoka. N. . 1985, Noble一gas state in the Earth's interior一some come constraints on the present state, Chemical Geology Isotope Geosickne section, 52:75一95.
3.徐永昌、王先彬、吴仁铭等,1979，天然气中稀有气体同位素，地球化学，(4):271-282。
4.徐永昌、沈平、肉明信等,199。二像氮的工业储集和郑庐大断裂带，科学通报，35(12):932-935。
5.徐永昌、沈平，1985，中原一华北油气区“煤蟹气”地球化学特征初探，沉积学报，3(2):37-46。
6.刘文汇、徐永昌，1987，天然气中红同位素组成及其与裸岩、箱层钾红关系.中国科学院兰州地质研究所生物气体地球化学开放研究实毅室 .1986研究年报，兰州:甘肃科学技术出版社，191-200。 -
点击查看大图
计量
- 文章访问数: 509
- HTML全文浏览量: 1
- PDF下载量: 421
- 被引次数: 0
下载:
