青海湖表层沉积物中Mo的分布特征及影响因素
- 收稿日期:
2023-04-05
- 网络出版日期:
2024-07-19
摘要: V/(V+Ni)、V/Cr、U/Th、U自生和Ce是海相地层传统的氧化还原判别指标,但对湖相地层氧化还原的判识出现多解性。钼(Mo)元素作为一个新的氧化还原判别指标,其在湖泊环境中的富集机制研究仍十分薄弱,限制了Mo在湖泊古环境重建中的应用潜力。本文对青海湖表层沉积物样品进行了系统性测试,分析了Mo的平面富集特征,探讨了Mo含量与沉积物陆源输入、粒度、元素含量、有机质含量及水体环境之间的相应关系。初步研究结果表明:青海湖目前属于碱性、弱氧化的微咸水湖泊,水体内Mo元素轻度富集于深水区沉积物。陆源输入及沉积物粒度不影响Mo的富集;弱碱性-碱性湖盆中Mo无法利用黏土矿物和铁(氢)氧化物吸附进行沉降与富集;锰-铁(氢)氧化物虽然有可能吸附Mo并发生沉降,但是随着沉积物表生作用转化为还原环境,Mo将会从沉积物内重新释放到水体。有机质丰度与Mo含量具有良好的相关性显示,深水区温跃层下底层水氧化性降低、还原性增强,有机质吸附及保存是沉积物中Mo富集的主控因素。
Distribution characteristics and influencing factors of Mo in surface sediments of Qinghai Lake
- Received Date:
2023-04-05
- Available Online:
2024-07-19
Abstract: V/(V+Ni), V/Cr, U/Th, Uauto and Ce are the traditional redox proxies of Marine strata, but there are multiple solutions to the redox identification of lacustrine strata. Molybdenum(Mo) is a new redox proxies, but the fixation mechanisms of Mo under various redox conditions in lake environment are not well understood, which limits the application potential of Mo in the reconstruction of lake paleoenvironment. This article systematically tested surface sediment samples from Qinghai Lake, analyzed the planar enrichment characteristics of Mo, and explored the corresponding relationships between Mo content and continental input, grain size, element content, organic matter content of sediment and water environment. The preliminary results show that Qinghai Lake is an alkaline, suboxic and brackish water lake, and Mo element is slightly enriched in the sediments in deep water area. Continental input and grain size of sediment do not affect Mo enrichment. Mo can not be settled and enriched by adsorption of clay minerals and Fe oxyhydroxides in weakly alkaline-alkaline lake basin. Although Mn oxyhydroxides may adsorb Mo and settle, Mo will be re-released from the sediment into the water body as the sediment transforms into a reducing environment. There is a good correlation between organic matter abundance and Mo content, indicating that, at the deep part of lake, the hypolimnion becomes dysoxic. Organic matter adsorption and preservation are the main controlling factors of Mo enrichment in sediments.