Molecular isotope (δ2H) composition traits and geological significance of petroleum n-alkanes in hinterland of Junggar Basin, NW China
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摘要: 【目的】准噶尔盆地中部地区地质条件多变,原油性质复杂,为了解决该地区原油类型划分和油气来源问题,对准中混源油进行原油正构烷烃氢同位素(δ2Halk)特征研究。【方法】应用GC-MS、GC-IRMS、GC-TC-IRMS技术,对33个不同层位原油饱和烃进行了生物标志化合物分析和正构烷烃单体氢同位素测试。【结果】将准中地区原油划分出三种类型:Ⅰ类原油来自侏罗系煤系烃源岩(J1b),由于有大量陆源高等植物有机质输入,使其氢同位素最轻;Ⅱ类原油主要来自二叠系风城组烃源岩(P1f),其中ⅡA原油来自海陆过渡环境的潟湖相沉积,Ga/C30H低,氢同位素较重,ⅡB原油正构烷烃氢同位素较轻,Ga/C30H比值较高;Ⅲ类原油主要来自二叠系下乌尔禾组烃源岩(P2w),正构烷烃氢同位素轻。【结论】将正构烷烃氢同位素与生物标志化合物手段相结合,可以精细划分原油类型,明确其来源,对整个准噶尔盆地油气勘探起到追踪油源并进行原油分类作用。Abstract: [Objective] The geological conditions in the hinterland Junggar Basin are diverse and the crude oil properties are complex. To address the issues of crude oil type classification and oil and gas source identification in this area, a study on the hydrogen isotopic characteristics of n-alkanes (δ2Halk) in the mixed-source crude oils from the hinterland Junggar Basin was conducted. [Methods] GC-MS, GC-IRMS, and GC-TC-IRMS techniques were employed to analyze biomarker compounds and conduct hydrogen isotope analysis of n-alkane monomers in 33 crude oil samples from different strata. [Results and Discussions] Three types of crude oil were identified in the hinterland Junggar Basin: Type I crude oil originated from the Jurassic coal-bearing source rocks (J1b), with the lightest hydrogen isotopic composition due to the significant input of terrestrial higher plant organic matter; Type II crude oil mainly originated from the Permian Fengcheng Formation source rocks (P1f), with Type IIA crude oil from lacustrine sedimentary environments in transitional marine-terrestrial settings, featuring a low Ga/C30H ratio and relatively heavy hydrogen isotopic composition, while Type IIB crude oil had a lighter hydrogen isotopic composition and a higher Ga/C30H ratio; Type III crude oil mainly originated from the Permian Lower Wuerhe Formation source rocks (P2w), with a light hydrogen isotopic composition of n-alkanes. [Conclusions] The combination of hydrogen isotopic analysis of n-alkanes and biomarker compound analysis can precisely classify crude oil types and clarify their sources, which is of great significance for oil source tracking and crude oil classification in the entire Junggar Basin.
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