塔里木盆地原油噻吩类化合物的组成特征及地球化学意义

张敏; 张俊

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塔里木盆地原油噻吩类化合物的组成特征及地球化学意义

张敏, 张俊

文章导航 > 沉积学报 > 1999 > 17(1): 120-126

张敏, 张俊. 塔里木盆地原油噻吩类化合物的组成特征及地球化学意义[J]. 沉积学报, 1999, 17(1): 120-126.

引用本文:

张敏, 张俊. 塔里木盆地原油噻吩类化合物的组成特征及地球化学意义[J]. 沉积学报, 1999, 17(1): 120-126.

Zhang Min, Zhang Jun. Composition Characteristics and Geochemical Significance of Thiophene-type Compounds for Crude Oils in Tarim Basin[J]. Acta Sedimentologica Sinica, 1999, 17(1): 120-126.

Citation:

Zhang Min, Zhang Jun. Composition Characteristics and Geochemical Significance of Thiophene-type Compounds for Crude Oils in Tarim Basin[J]. Acta Sedimentologica Sinica, 1999, 17(1): 120-126.

张敏, 张俊. 塔里木盆地原油噻吩类化合物的组成特征及地球化学意义[J]. 沉积学报, 1999, 17(1): 120-126.

引用本文:

张敏, 张俊. 塔里木盆地原油噻吩类化合物的组成特征及地球化学意义[J]. 沉积学报, 1999, 17(1): 120-126.

Zhang Min, Zhang Jun. Composition Characteristics and Geochemical Significance of Thiophene-type Compounds for Crude Oils in Tarim Basin[J]. Acta Sedimentologica Sinica, 1999, 17(1): 120-126.

Citation:

Zhang Min, Zhang Jun. Composition Characteristics and Geochemical Significance of Thiophene-type Compounds for Crude Oils in Tarim Basin[J]. Acta Sedimentologica Sinica, 1999, 17(1): 120-126.

塔里木盆地原油噻吩类化合物的组成特征及地球化学意义

张敏,
张俊

江汉石油学院地球化学研究中心,湖北荆州 434102

详细信息

作者简介:
张敏，男，36岁，博士，副教授，有机地球化学与石油地质。

中图分类号: P593;P593

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文章访问数: 511
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Composition Characteristics and Geochemical Significance of Thiophene-type Compounds for Crude Oils in Tarim Basin

The Geochemistry Research Center of Jianghan Petroleum Institute,Jingzhou Hubei 434102

摘要

摘要: 对塔里木盆地典型原油噻吩类化合物含量和组成特征研究，发现不同类型原油苯并萘噻吩和二苯并噻吩系列化合物占芳烃化合物的百分含量相差明显，海相油含量最高，湖相油次之，而煤成油最低。本文提出了４－甲基二苯并噻吩／二苯并噻吩、（２＋３）－甲基二苯并噻吩／二苯并噻吩比值是区分海相油和湖相油新的有机地球化学参数。二苯并噻吩系列化合物最大烷化度表明海相油呈现出高烷化度，而陆相油则表现为低烷化度，即从海相泥灰岩原油、海相碳酸盐岩原油到湖相油和煤成油依次减少。这是因为富硫与贫硫干酪根在生烃过程中的环化作用或支链化作用程度差异所造成的。
- 二苯并噻吩 /
- 海相油 /
- 湖相油 /
- 煤成油 /
- 塔里木盆地
Abstract: The relative abundance and composition characteristics of thiophene-type compounds for typical crude oils in Tarin Basin were analysed and studied systematically using GC-MS-MS technique. The results suggest the relative abundance between benzonaphiothiophene and dibenzothiophene series of % toatal polycyclic aromatic hydrocarbons for different types of crude oils are obvious differences,the contents of marine oils are the higest,contents of lacustrine oils are lower and that of coal-forming oils are the lowest.In this paper,we propose some new organic geochemical parameters for distinguishing marine oil and lacustrine oil using the ratio values of 4-dimethyldibenzothiophene(MDBT)/dibenzothiophene(DBT) as well as (2+3)-MDBT/DBT,for distinguishing marine marl-sourced oil and marine carbonate-sourced oil using the ratio value of 1-MDBT/DBT.Marine oils and coal-forming oils show a predominance of alkylated DBT homologues over the unsubstituted parent,but laustrine oils differ from marine oils and coal-forming oils.However,the maximum degree of alkylation(the most abundance alkylation homologues within any given DBT series) varies,marine oils show a high degree of alkylation,which non-marine oils generally exhibit a lower degree of alkylation.So there is increasing decrease trends from marine marl-sourced oils and marine carbonat-sourced oils to laustrine oils and coal-forming oils.We propose that alkylation trends reflect differences of crosslinking or branching on aliphatic and cyclic moieties in sulfur-rich vs.sulfur-poor kcrogens.
- dibenzothiophene /
- marine oil /
- lacustrine oil /
- coal-forming oil /
- Tarim Basin

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参考文献(1)

[1]

1.Fan P;Philp R P;Zhenxi L;Guangguo Y Geochemical characteristics of aromatic hydrocarbons of crude oils and source rocksfrom different sedimentary environments 1991

2.Hughes W B;Holba A G;Dzou L I P The ratios of dibenzothiophene to phenanthrene and pristane to phytane as indicators of depositional environment and lithology of petroleum source rocks[外文期刊] 1995

3.Chakhmakhchev A;Suzuki N Saturate biomarkers and aromatic sulfur compounds in iols and condensates from different sourcerock lithologies of Kazakhstan,Japan and Russia 1995(01)

4.Chakhmakhchev A;Suzuki N Aromatic sulfur compounds as maturity indicators for overmature petroleum from the Buzuluk depression Russia 1995(02)

5.Chakhmakhchev A;Suzuki N;Takayama K Distribution of alkylated dibenzothiophenes in petroleum as a tool for maturity assessments[外文期刊] 1997

6.张敏;朱扬明塔里木盆地库车油气系统原油地球化学特征[期刊论文]-地质论评 1996(ZK)

7.张敏;林壬子;梅博文油藏地球化学--塔里木盆地库车含油气系统研究 1998

8.Requejo A G;Sassen R;Mcdonald T Polynuclar aromatic hydrocarbons (PHA) as indications of the source and maturity of marine crude oils 1996

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塔里木盆地原油噻吩类化合物的组成特征及地球化学意义

张敏,
张俊

江汉石油学院地球化学研究中心,湖北荆州 434102

作者简介:
张敏，男，36岁，博士，副教授，有机地球化学与石油地质。

收稿日期: 1998-01-16
修回日期: 1998-04-30
刊出日期: 1999-03-10

中图分类号: P593;P593

关键词:

二苯并噻吩 /

海相油 /

湖相油 /

煤成油 /

塔里木盆地

摘要: 对塔里木盆地典型原油噻吩类化合物含量和组成特征研究，发现不同类型原油苯并萘噻吩和二苯并噻吩系列化合物占芳烃化合物的百分含量相差明显，海相油含量最高，湖相油次之，而煤成油最低。本文提出了４－甲基二苯并噻吩／二苯并噻吩、（２＋３）－甲基二苯并噻吩／二苯并噻吩比值是区分海相油和湖相油新的有机地球化学参数。二苯并噻吩系列化合物最大烷化度表明海相油呈现出高烷化度，而陆相油则表现为低烷化度，即从海相泥灰岩原油、海相碳酸盐岩原油到湖相油和煤成油依次减少。这是因为富硫与贫硫干酪根在生烃过程中的环化作用或支链化作用程度差异所造成的。

English Abstract

Composition Characteristics and Geochemical Significance of Thiophene-type Compounds for Crude Oils in Tarim Basin

The Geochemistry Research Center of Jianghan Petroleum Institute,Jingzhou Hubei 434102

Received Date: 1998-01-16
Rev Recd Date: 1998-04-30
Publish Date: 1999-03-10

Keywords:

Abstract: The relative abundance and composition characteristics of thiophene-type compounds for typical crude oils in Tarin Basin were analysed and studied systematically using GC-MS-MS technique. The results suggest the relative abundance between benzonaphiothiophene and dibenzothiophene series of % toatal polycyclic aromatic hydrocarbons for different types of crude oils are obvious differences,the contents of marine oils are the higest,contents of lacustrine oils are lower and that of coal-forming oils are the lowest.In this paper,we propose some new organic geochemical parameters for distinguishing marine oil and lacustrine oil using the ratio values of 4-dimethyldibenzothiophene(MDBT)/dibenzothiophene(DBT) as well as (2+3)-MDBT/DBT,for distinguishing marine marl-sourced oil and marine carbonate-sourced oil using the ratio value of 1-MDBT/DBT.Marine oils and coal-forming oils show a predominance of alkylated DBT homologues over the unsubstituted parent,but laustrine oils differ from marine oils and coal-forming oils.However,the maximum degree of alkylation(the most abundance alkylation homologues within any given DBT series) varies,marine oils show a high degree of alkylation,which non-marine oils generally exhibit a lower degree of alkylation.So there is increasing decrease trends from marine marl-sourced oils and marine carbonat-sourced oils to laustrine oils and coal-forming oils.We propose that alkylation trends reflect differences of crosslinking or branching on aliphatic and cyclic moieties in sulfur-rich vs.sulfur-poor kcrogens.

张敏, 张俊. 塔里木盆地原油噻吩类化合物的组成特征及地球化学意义[J]. 沉积学报, 1999, 17(1): 120-126.

引用本文:

张敏, 张俊. 塔里木盆地原油噻吩类化合物的组成特征及地球化学意义[J]. 沉积学报, 1999, 17(1): 120-126.

Zhang Min, Zhang Jun. Composition Characteristics and Geochemical Significance of Thiophene-type Compounds for Crude Oils in Tarim Basin[J]. Acta Sedimentologica Sinica, 1999, 17(1): 120-126.

Citation:

Zhang Min, Zhang Jun. Composition Characteristics and Geochemical Significance of Thiophene-type Compounds for Crude Oils in Tarim Basin[J]. Acta Sedimentologica Sinica, 1999, 17(1): 120-126.

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塔里木盆地原油噻吩类化合物的组成特征及地球化学意义

作者简介:
张敏，男，36岁，博士，副教授，有机地球化学与石油地质。

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Composition Characteristics and Geochemical Significance of Thiophene-type Compounds for Crude Oils in Tarim Basin

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塔里木盆地原油噻吩类化合物的组成特征及地球化学意义

江汉石油学院地球化学研究中心,湖北荆州 434102

作者简介:
张敏，男，36岁，博士，副教授，有机地球化学与石油地质。

English Abstract

Composition Characteristics and Geochemical Significance of Thiophene-type Compounds for Crude Oils in Tarim Basin

The Geochemistry Research Center of Jianghan Petroleum Institute,Jingzhou Hubei 434102

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塔里木盆地原油噻吩类化合物的组成特征及地球化学意义

作者简介: 张敏，男，36岁，博士，副教授，有机地球化学与石油地质。

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Composition Characteristics and Geochemical Significance of Thiophene-type Compounds for Crude Oils in Tarim Basin

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出版历程

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塔里木盆地原油噻吩类化合物的组成特征及地球化学意义

江汉石油学院地球化学研究中心,湖北荆州 434102

作者简介: 张敏，男，36岁，博士，副教授，有机地球化学与石油地质。

English Abstract

Composition Characteristics and Geochemical Significance of Thiophene-type Compounds for Crude Oils in Tarim Basin

The Geochemistry Research Center of Jianghan Petroleum Institute,Jingzhou Hubei 434102

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目录

友情链接

期刊在线

联系我们

作者简介:
张敏，男，36岁，博士，副教授，有机地球化学与石油地质。

作者简介:
张敏，男，36岁，博士，副教授，有机地球化学与石油地质。