应用TGA-FTIR测定煤显微组分的生烃动力学参数

张英; 蒋助生; Lloyd Snow done; Dale Isslere

ISSN 1000-0550 CN 62-1038/P

高级搜索

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

应用TGA-FTIR测定煤显微组分的生烃动力学参数

张英, 蒋助生, Lloyd Snow done, Dale Isslere

文章导航 > 沉积学报 > 1997 > 15(2): 122-125

张英, 蒋助生, Lloyd Snow done, Dale Isslere. 应用TGA-FTIR测定煤显微组分的生烃动力学参数[J]. 沉积学报, 1997, 15(2): 122-125.

引用本文:

张英, 蒋助生, Lloyd Snow done, Dale Isslere. 应用TGA-FTIR测定煤显微组分的生烃动力学参数[J]. 沉积学报, 1997, 15(2): 122-125.

Zhang Ying, Jiang Zhusheng, Lloyd Snow done, Dale Isslere. Using TGA-FTIR to Determine Kinetic Parameters of Coal Macerals[J]. Acta Sedimentologica Sinica, 1997, 15(2): 122-125.

Citation:

Zhang Ying, Jiang Zhusheng, Lloyd Snow done, Dale Isslere. Using TGA-FTIR to Determine Kinetic Parameters of Coal Macerals[J]. Acta Sedimentologica Sinica, 1997, 15(2): 122-125.

张英, 蒋助生, Lloyd Snow done, Dale Isslere. 应用TGA-FTIR测定煤显微组分的生烃动力学参数[J]. 沉积学报, 1997, 15(2): 122-125.

引用本文:

张英, 蒋助生, Lloyd Snow done, Dale Isslere. 应用TGA-FTIR测定煤显微组分的生烃动力学参数[J]. 沉积学报, 1997, 15(2): 122-125.

Zhang Ying, Jiang Zhusheng, Lloyd Snow done, Dale Isslere. Using TGA-FTIR to Determine Kinetic Parameters of Coal Macerals[J]. Acta Sedimentologica Sinica, 1997, 15(2): 122-125.

Citation:

Zhang Ying, Jiang Zhusheng, Lloyd Snow done, Dale Isslere. Using TGA-FTIR to Determine Kinetic Parameters of Coal Macerals[J]. Acta Sedimentologica Sinica, 1997, 15(2): 122-125.

应用TGA-FTIR测定煤显微组分的生烃动力学参数

1 石油天然气总公司勘探开发科学研究院廊坊分院河北廊坊 102801;
2 Geological Survey of Canada Calgary

详细信息

作者简介:
张英女助理工程师有机地球化学

中图分类号: P618.11

计量

文章访问数: 742
HTML全文浏览量: 117
PDF下载量: 559
被引次数: 0

Using TGA-FTIR to Determine Kinetic Parameters of Coal Macerals

1 Langfang Branch Reaserch Institute of RIPED CN PC Hebei Longfang 102801;
2 Geological Survey of Canada Calgary

摘要

摘要: 天然气生成的动力学参数的求取一直是天然气勘探盆地模拟技术中的难题。本文应用一套ＴＧＡ－ＦＴＩＲ（热失重与傅利叶红外光谱联用仪）对不同煤显微组分进行了分析，并将结果代入ｌｓｓｌｅｒ的最优化软件系统，求取这些组分的热解产物动力学方程，并对其热解性质进行了探讨。这些动力学方程可直接用于盆地模拟软件系统中，预测甲烷及其它产物的生成史。
- 煤显微组分 /
- TGA－FTIR热解 /
- 天然气生成 /
- 动力学参数
Abstract: Kinetic parameters of kerogen pyrolysis have been widely used in basin modelling. Because the de-tection of gas products is more difficult than that of liquid products in thermal simulation experiments,the study of natural gas generation is random. The combination of TG( thermogravimetric)analysis with Fourier transform infrared(FTIR) spec-troscopy analysis was used to analyze different coal macerals and detect the pyrolysis products. The powdered samples were grogerssively heatedcatra to of 25℃/minute) and weighted in theT G A. A carrier gas transported the effluent through a multipass gas cell for continuos analysis by FTIRSelected infrared absorption bands were used to detect different compounds. Data were captured foraliphatics, aromatics, cardon dioxide and methane. The analytical results indicated that different coal macerals have different characters in pyrolysis. Hydrocarbon generation can be modelled by assuming that a number of parallel first grder reactions control the thermal decomposition of kerogen. Issler's optimization software was used to derive kineticparameters from the digitized pyrolysis traces. Kinetic solutions from TGA-FTIR data yield equations forspecial products. Inputting this equatioins into a numerical modelling package such as BASINMO D, alongwith other information, the generation of methane, aliphatics etc.coilld be predicted.
- coal macerals /
- TGA一TIR pyrolysis /
- natural gas generation /
- kinetic parameter

HTML全文

参考文献(1)

[1]

1 W helan ,J Carangelo R Solomon P R etch GT/plus a Py rolysisrnethnrl for following maturation of oil and gas Generation Zones Using Tmax of Methane, Oxg. Geochcm.1990, 16 (4-6)：1187-1201

2 Issler D R Deterimation of Kinetic Parameters for Hvdrocar-bon Generatinn An Instrirtinn Manual for using a Kinetic Optimization SoftwarePackage Geological Survey of Canada Open file Report 3001,199523

[1]	. 原油裂解成气动力学参数及其应用研究 . 沉积学报, 2012, 30(6): 1156-1164.
[2]	. 煤岩、泥岩密闭体系下热解产物特征及动力学分析 . 沉积学报, 2011, 29(6): 1190-1198.
[3]	靳永斌. 正构二十四烷裂解成气碳同位素动力学模拟及其地质意义 . 沉积学报, 2009, 27(3): 537-545.
[4]	张长春. 吐哈盆地丘东次凹低熟气的生成与动力学研究 . 沉积学报, 2008, 26(5): 857-863.
[5]	王秀红. 东营凹陷民丰地区天然气生成机理与化学动力学研究 . 沉积学报, 2008, 26(3): 525-530.
[6]	刘成林, 刘人和, 罗霞, 谢增业, 李剑, 曾庆猛. 天然气资源评价重点参数研究 . 沉积学报, 2004, 22(S1): 79-83.
[7]	田春志, 卢双舫, 李启明, 付晓泰, 薛海涛. 塔里木盆地原油高压条件下裂解成气的化学动力学模型及其意义 . 沉积学报, 2002, 20(3): 488-492.
[8]	张瑞生, 王华, 吴冲龙. 抚顺盆地沉积动力学特征及其聚煤意义 . 沉积学报, 2001, 19(3): 375-380.
[9]	卢双舫, 刘晓艳, 付晓泰, 冯亚丽, 王振平, 薛海涛. 未熟—低熟油生成机理的化学动力学研究及其初步应用 . 沉积学报, 2001, 19(1): 130-135.
[10]	黄华芳, 刘子贵, 周晓峰. 中国主要含气盆地构造动力学类型与天然气地质条件 . 沉积学报, 1999, 17(S1): 805-810.
[11]	王国安, 申建中, 季美英. 塔北天然气组分特征及同位素组成 . 沉积学报, 1998, 16(4): 128-132.
[12]	沈忠民, 周光甲, 洪志华. 陆相低成熟烃源岩有机硫与热解成烃动力学关系初探 . 沉积学报, 1998, 16(4): 133-139.
[13]	王雅春, 庞雄奇, 卢双舫. 地史过程中煤岩显微组分含量的恢复及其意义 . 沉积学报, 1998, 16(4): 114-117.
[14]	高岗, 刚文哲, 郝石生. 奥陶系未成熟藻干酪根水解下动力学参数的计算 . 沉积学报, 1998, 16(4): 140-144.
[15]	卢双舫, 陈昕, 付晓泰. 台北凹陷煤中有机质的成烃动力学模型及其初步应用 . 沉积学报, 1997, 15(2): 126-129.
[16]	李术元, 郭绍辉, 徐红喜, 王剑秋. 烃源岩热解生烃动力学及其应用 . 沉积学报, 1997, 15(2): 138-141.
[17]	卢双舫, 王子文, 付晓泰, 王振平. 镜质体成烃反应动力学模型的标定及其在热史恢复中的应用 . 沉积学报, 1996, 14(4): 24-30.
[18]	姚素平, 张景荣, 金奎励. 用显微荧光和显微傅立叶红外光谱研究显微组分的热演化规律 . 沉积学报, 1996, 14(3): 1-10.
[19]	丁安娜, 张中宁, 惠荣耀. 煤岩显微组份和全煤热解色谱分析 . 沉积学报, 1994, 12(4): 87-94.
[20]	杜建国, 刘文汇, 孙明良. 广东三水盆地天然气非烃组分同位素地球化学 . 沉积学报, 1991, 9(1): 97-105.

施引文献

资源附件(0)

访问统计

点击查看大图

计量

文章访问数: 742
HTML全文浏览量: 117
PDF下载量: 559
被引次数: 0

应用TGA-FTIR测定煤显微组分的生烃动力学参数

1 石油天然气总公司勘探开发科学研究院廊坊分院河北廊坊 102801;

2 Geological Survey of Canada Calgary

作者简介:
张英女助理工程师有机地球化学

收稿日期: 1996-09-12
刊出日期: 1997-04-10

中图分类号: P618.11

关键词:

摘要: 天然气生成的动力学参数的求取一直是天然气勘探盆地模拟技术中的难题。本文应用一套ＴＧＡ－ＦＴＩＲ（热失重与傅利叶红外光谱联用仪）对不同煤显微组分进行了分析，并将结果代入ｌｓｓｌｅｒ的最优化软件系统，求取这些组分的热解产物动力学方程，并对其热解性质进行了探讨。这些动力学方程可直接用于盆地模拟软件系统中，预测甲烷及其它产物的生成史。

English Abstract

Using TGA-FTIR to Determine Kinetic Parameters of Coal Macerals

1 Langfang Branch Reaserch Institute of RIPED CN PC Hebei Longfang 102801;

2 Geological Survey of Canada Calgary

Received Date: 1996-09-12
Publish Date: 1997-04-10

Keywords:

Abstract: Kinetic parameters of kerogen pyrolysis have been widely used in basin modelling. Because the de-tection of gas products is more difficult than that of liquid products in thermal simulation experiments,the study of natural gas generation is random. The combination of TG( thermogravimetric)analysis with Fourier transform infrared(FTIR) spec-troscopy analysis was used to analyze different coal macerals and detect the pyrolysis products. The powdered samples were grogerssively heatedcatra to of 25℃/minute) and weighted in theT G A. A carrier gas transported the effluent through a multipass gas cell for continuos analysis by FTIRSelected infrared absorption bands were used to detect different compounds. Data were captured foraliphatics, aromatics, cardon dioxide and methane. The analytical results indicated that different coal macerals have different characters in pyrolysis. Hydrocarbon generation can be modelled by assuming that a number of parallel first grder reactions control the thermal decomposition of kerogen. Issler's optimization software was used to derive kineticparameters from the digitized pyrolysis traces. Kinetic solutions from TGA-FTIR data yield equations forspecial products. Inputting this equatioins into a numerical modelling package such as BASINMO D, alongwith other information, the generation of methane, aliphatics etc.coilld be predicted.

张英, 蒋助生, Lloyd Snow done, Dale Isslere. 应用TGA-FTIR测定煤显微组分的生烃动力学参数[J]. 沉积学报, 1997, 15(2): 122-125.

引用本文:

张英, 蒋助生, Lloyd Snow done, Dale Isslere. 应用TGA-FTIR测定煤显微组分的生烃动力学参数[J]. 沉积学报, 1997, 15(2): 122-125.

Zhang Ying, Jiang Zhusheng, Lloyd Snow done, Dale Isslere. Using TGA-FTIR to Determine Kinetic Parameters of Coal Macerals[J]. Acta Sedimentologica Sinica, 1997, 15(2): 122-125.

Citation:

Zhang Ying, Jiang Zhusheng, Lloyd Snow done, Dale Isslere. Using TGA-FTIR to Determine Kinetic Parameters of Coal Macerals[J]. Acta Sedimentologica Sinica, 1997, 15(2): 122-125.

全文HTML

参考文献 (1)

下载: 全尺寸图片幻灯片

返回文章

用微信扫码二维码

分享至好友和朋友圈

留言板

应用TGA-FTIR测定煤显微组分的生烃动力学参数

作者简介:
张英女助理工程师有机地球化学

计量

Using TGA-FTIR to Determine Kinetic Parameters of Coal Macerals

计量

目录

应用TGA-FTIR测定煤显微组分的生烃动力学参数

1 石油天然气总公司勘探开发科学研究院廊坊分院河北廊坊 102801;

2 Geological Survey of Canada Calgary

作者简介:
张英女助理工程师有机地球化学

English Abstract

Using TGA-FTIR to Determine Kinetic Parameters of Coal Macerals

1 Langfang Branch Reaserch Institute of RIPED CN PC Hebei Longfang 102801;

2 Geological Survey of Canada Calgary

全文HTML

目录

友情链接

期刊在线

联系我们

留言板

应用TGA-FTIR测定煤显微组分的生烃动力学参数

作者简介: 张英 女 助理 工程师 有机地球化学

计量

出版历程

Using TGA-FTIR to Determine Kinetic Parameters of Coal Macerals

计量

出版历程

目录

应用TGA-FTIR测定煤显微组分的生烃动力学参数

1 石油天然气总公司勘探开发科学研究院廊坊分院 河北廊坊 102801; 2 Geological Survey of Canada Calgary

作者简介: 张英 女 助理 工程师 有机地球化学

English Abstract

Using TGA-FTIR to Determine Kinetic Parameters of Coal Macerals

1 Langfang Branch Reaserch Institute of RIPED CN PC Hebei Longfang 102801; 2 Geological Survey of Canada Calgary

全文HTML

目录

友情链接

期刊在线

联系我们

作者简介:
张英女助理工程师有机地球化学

1 石油天然气总公司勘探开发科学研究院廊坊分院河北廊坊 102801;

2 Geological Survey of Canada Calgary

作者简介:
张英女助理工程师有机地球化学

1 Langfang Branch Reaserch Institute of RIPED CN PC Hebei Longfang 102801;

2 Geological Survey of Canada Calgary